View source for Paramagnetism

{{short description|Weak, attractive magnetism possessed by most elements and some compounds}}
[[File:Liquid oxygen in a magnet 2.jpg|thumb|Liquid oxygen (blue) can be suspended between the poles of a strong magnet as a result of its paramagnetism.]]
{{Condensed matter physics}}
'''Paramagnetism''' is a form of [[magnetism]] whereby some materials are weakly attracted by an externally applied [[magnetic field]], and form internal, [[Magnetization|induced magnetic field]]s in the direction of the applied magnetic field. In contrast with this behavior, [[diamagnetism|diamagnetic]] materials are repelled by magnetic fields and form induced magnetic fields in the direction opposite to that of the applied magnetic field.<ref>Miessler, G. L. and Tarr, D. A. (2010) ''Inorganic Chemistry'' 3rd ed., Pearson/Prentice Hall publisher, {{ISBN|0-13-035471-6}}.</ref> Paramagnetic materials include most [[chemical element]]s and some [[Chemical compound|compounds]];<ref name=brit/> they have a relative [[magnetic permeability]] slightly greater than 1 (i.e., a small positive [[magnetic susceptibility]]) and hence are attracted to magnetic fields. The [[magnetic moment]] induced by the applied field is linear in the field strength and rather weak. It typically requires a sensitive analytical balance to detect the effect and modern measurements on paramagnetic materials are often conducted with a [[SQUID]] [[magnetometer]].

Paramagnetism is due to the presence of [[unpaired electron]]s in the material, so most atoms with incompletely filled [[atomic orbital]]s are paramagnetic, although exceptions such as copper exist.  Due to their [[Spin (physics)|spin]], unpaired electrons have a [[magnetic dipole moment]] and act like tiny magnets.  An external magnetic field causes the electrons' spins to align parallel to the field, causing a net attraction. Paramagnetic materials include [[aluminium]], [[oxygen]], [[titanium]], and [[iron oxide]] (FeO). Therefore, a simple [[rule of thumb]] is used in chemistry to determine whether a particle (atom, ion, or molecule) is paramagnetic or diamagnetic:<ref>{{Cite web|url=https://chem.libretexts.org/Bookshelves/Physical_and_Theoretical_Chemistry_Textbook_Maps/Supplemental_Modules_(Physical_and_Theoretical_Chemistry)/Physical_Properties_of_Matter/Atomic_and_Molecular_Properties/Magnetic_Properties|title=Magnetic Properties|date=2013-10-02|website=Chemistry LibreTexts|language=en|access-date=2020-01-21}}</ref> if all electrons in the particle are paired, then the substance made of this particle is diamagnetic; if it has unpaired electrons, then the substance is paramagnetic.

Unlike [[ferromagnetism|ferromagnets]], paramagnets do not retain any magnetization in the absence of an externally applied magnetic field because [[thermal motion]] randomizes the spin orientations. (Some paramagnetic materials retain spin disorder even at [[absolute zero]], meaning they are paramagnetic in the [[ground state]], i.e. in the absence of thermal motion.) Thus the total magnetization drops to zero when the applied field is removed. Even in the presence of the field there is only a small induced magnetization because only a small fraction of the spins will be oriented by the field. This fraction is proportional to the field strength and this explains the linear dependency. The attraction experienced by ferromagnetic materials is non-linear and much stronger, so that it is easily observed, for instance, in the attraction between a [[refrigerator magnet]] and the iron of the refrigerator itself.

==Relation to electron spins==
[[File:Paramagnetism, ferromagnetism and spin waves.webm|thumb|Paramagnetism, ferromagnetism and spin waves]]

Constituent atoms or molecules of paramagnetic materials have permanent magnetic moments ([[dipole]]s), even in the absence of an applied field. The permanent moment generally is due to the spin of unpaired electrons in [[Atomic orbital|atomic]] or [[Molecular orbital|molecular electron orbitals]] (see [[Magnetic moment]]).  In pure paramagnetism, the  [[dipoles]] do not interact with one another and are randomly oriented in the absence of an external field due to thermal agitation, resulting in zero net magnetic moment. When a magnetic field is applied, the dipoles will tend to align with the applied field, resulting in a net magnetic moment in the direction of the applied field. In the classical description, this alignment can be understood to occur due to a [[torque]] being provided on the magnetic moments by an applied field, which tries to align the dipoles parallel to the applied field. However, the true origins of the alignment can only be understood via the [[quantum mechanics|quantum-mechanical]] properties of [[Spin (physics)|spin]] and [[angular momentum]].

If there is sufficient energy exchange between neighbouring dipoles, they will interact, and may spontaneously align or anti-align and form magnetic domains, resulting in [[ferromagnetism]] (permanent magnets) or [[antiferromagnetism]], respectively. Paramagnetic behavior can also be observed in ferromagnetic materials that are above their [[Curie temperature]], and in antiferromagnets above their [[Néel temperature]]. At these temperatures, the available thermal energy simply overcomes the interaction energy between the spins.

In general, paramagnetic effects are quite small: the [[magnetic susceptibility]] is of the order of 10<sup>−3</sup> to 10<sup>−5</sup> for most paramagnets, but may be as high as 10<sup>−1</sup> for synthetic paramagnets such as [[ferrofluid]]s.

===Delocalization===
{|class="wikitable sortable" style="float:right; margin:20px" width="200px"
|+ Selected Pauli-paramagnetic metals<ref name="magneticValues">{{Cite web|url=http://hyperphysics.phy-astr.gsu.edu/Hbase/tables/magprop.html|title=Magnetic Properties of Solids|last=Nave|first=Carl L|work=HyperPhysics|access-date=2008-11-09}}</ref>
!Material!!Magnetic susceptibility, <math>\chi_v</math> [10<sup>−5</sup>]

(SI units)
|-
|[[Tungsten]]||6.8
|-
|[[Caesium]]||5.1
|-
|[[Aluminium]]||2.2
|-
|[[Lithium]]||1.4
|-
|[[Magnesium]]||1.2
|-
|[[Sodium]]||0.72
|}

In conductive materials, the electrons are [[delocalized]], that is, they travel through the solid more or less as [[Free particle|free electrons]]. Conductivity can be understood in a [[band structure]] picture as arising from the incomplete filling of energy bands.
In an ordinary nonmagnetic conductor the conduction band is identical for both spin-up and spin-down electrons. When a magnetic field is applied, the conduction band splits apart into a spin-up and a spin-down band due to the difference in [[magnetic potential energy]] for spin-up and spin-down electrons.
Since the [[Fermi level]] must be identical for both bands, this means that there will be a small surplus of the type of spin in the band that moved downwards. This effect is a weak form of paramagnetism known as ''Pauli paramagnetism''.

The effect always competes with a [[diamagnetic]] response of opposite sign due to all the core electrons of the atoms. Stronger forms of magnetism usually require localized rather than itinerant electrons. However, in some cases a band structure can result in which there are two delocalized sub-bands with states of opposite spins that have different energies. If one subband is preferentially filled over the other, one can have itinerant ferromagnetic order. This situation usually only occurs in relatively narrow (d-)bands, which are poorly delocalized.

====s and p electrons====
Generally, strong delocalization in a solid due to large overlap with neighboring wave functions means that there will be a large [[Fermi velocity]]; this means that the number of electrons in a band is less sensitive to shifts in that band's energy, implying a weak magnetism. This is why s- and p-type metals are typically either Pauli-paramagnetic or as in the case of gold even diamagnetic. In the latter case the diamagnetic contribution from the closed shell inner electrons simply wins over the weak paramagnetic term of the almost free electrons.

====d and f electrons====
Stronger magnetic effects are typically only observed when d or f electrons are involved. Particularly the latter are usually strongly localized. Moreover, the size of the magnetic moment on a lanthanide atom can be quite large as it can carry up to 7 unpaired electrons in the case of [[gadolinium]](III) (hence its use in [[MRI]]). The high magnetic moments associated with lanthanides is one reason why [[rare-earth magnet|superstrong magnets]] are typically based on elements like [[neodymium]] or [[samarium]].

====Molecular localization====
The above picture is a ''generalization'' as it pertains to materials with an extended lattice rather than a molecular structure. Molecular structure can also lead to localization of electrons. Although there are usually energetic reasons why a molecular structure results such that it does not exhibit partly filled orbitals (i.e. unpaired spins), some non-closed shell moieties do occur in nature. Molecular oxygen is a good example. Even in the frozen solid it contains [[diradical|di-radical molecules]] resulting in paramagnetic behavior. The unpaired spins reside in orbitals derived from oxygen p wave functions, but the overlap is limited to the one neighbor in the O<sub>2</sub> molecules. The distances to other oxygen atoms in the lattice remain too large to lead to delocalization and the magnetic moments remain unpaired.

==Theory==
The [[Bohr–Van Leeuwen theorem]] proves that there cannot be any diamagnetism or paramagnetism in a purely classical system. The paramagnetic response has then two possible quantum origins, either coming from permanent magnetic moments of the ions or from the spatial motion of the conduction electrons inside the material. Both descriptions are given below.

===Curie's law ===
{{main|Curie's law}}
For low levels of magnetization, the magnetization of paramagnets follows what is known as [[Curie's law]], at least approximately.  This law indicates that the susceptibility, <math> \chi</math>, of paramagnetic materials is inversely proportional to their temperature, i.e. that materials become more magnetic at lower temperatures.  The mathematical expression is:
<math display="block"> \mathbf{M} = \chi\mathbf{H} = \frac{C}{T}\mathbf{H}</math>
where:
*<math>\mathbf M</math> is the resulting magnetization, measured in [[ampere]]s/meter (A/m),
*<math>\chi</math> is the [[magnetic susceptibility|volume magnetic susceptibility]] ([[Dimensionless quantity|dimensionless]]),
*<math>H</math> is the auxiliary [[magnetic field]] (A/m),
*<math>T</math> is absolute temperature, measured in [[kelvin]]s (K),
*<math>C</math> is a material-specific [[Curie constant]] (K).

Curie's law is valid under the commonly encountered conditions of low magnetization (''μ''<sub>B</sub>''H'' ≲ ''k''<sub>B</sub>''T''), but does not apply in the high-field/low-temperature regime where saturation of magnetization occurs (''μ''<sub>B</sub>''H'' ≳ ''k''<sub>B</sub>''T'') and magnetic dipoles are all aligned with the applied field. When the dipoles are aligned, increasing the external field will not increase the total magnetization since there can be no further alignment.

For a paramagnetic ion with noninteracting magnetic moments with angular momentum ''J'', the Curie constant is related to the individual ions' magnetic moments,
<math display="block">C=\frac{n}{3k_\mathrm{B}}\mu_{\mathrm{eff}}^2 \text{ where } \mu_{\mathrm{eff}} = g_J \mu_\mathrm{B} \sqrt{J(J+1)}.</math>

where ''n'' is the number of atoms per unit volume. The parameter ''μ''<sub>eff</sub> is interpreted as the effective magnetic moment per paramagnetic ion.  If one uses a classical treatment with molecular magnetic moments represented as discrete magnetic dipoles, ''μ'', a Curie Law expression of the same form will emerge with ''μ'' appearing in place of ''μ''<sub>eff</sub>.

{{math proof | title = Derivation | proof =
Curie's Law can be derived  by considering a substance with noninteracting magnetic moments with angular momentum ''J''.  If orbital contributions to the magnetic moment are negligible (a common case), then in what follows ''J'' = ''S''.  If we apply a magnetic field along what we choose to call the ''z''-axis, the energy levels of each paramagnetic center will experience [[Zeeman splitting]] of its energy levels, each with a ''z''-component labeled by ''M<sub>J</sub>'' (or just  ''M<sub>S</sub>'' for the spin-only magnetic case).  Applying semiclassical [[Boltzmann statistics]], the magnetization of such a substance is
<math display="block">n\bar{m} = \frac{n\sum\limits_{M_{J} = -J}^{J}{\mu_{M_{J}}e^{{-E_{M_{J}}}/{k_{\mathrm{B}}T}\;}}}{\sum\limits_{M_{J} = -J}^{J}{e^{{-E_{M_{J}}}/{k_{\mathrm{B}}T}\;}}} = \frac{n\sum\limits_{M_{J} = -J}^{J}{M_{J}g_{J}\mu_{\mathrm{B}}e^{{M_{J}g_{J}\mu_{\mathrm{B}}H}/{k_{\mathrm{B}}T}\;}}}{\sum\limits_{M_{J} = -J}^{J}{e^{{M_{J}g_{J}\mu_{\mathrm{B}}H}/{k_{\mathrm{B}}T}\;}}}.</math>

Where <math>\mu_{M_J}</math> is the ''z''-component of the magnetic moment for each Zeeman level, so <math>\mu _{M_J} = M_J g_J\mu_\mathrm{B} - \mu_\mathrm{B}</math> is called the [[Bohr magneton]] and ''g''<sub>''J''</sub> is the [[Landé g-factor]], which reduces to the free-electron g-factor, ''g''<sub>''S''</sub> when&nbsp;''J''&nbsp;=&nbsp;''S''.  (in this treatment, we assume that the ''x''- and ''y''-components of the magnetization, averaged over all molecules, cancel out because the field applied along the ''z''-axis leave them randomly oriented.)  The energy of each Zeeman level is <math>E_{M_J} = -M_J g_J \mu_\mathrm{B} H</math>.  For temperatures over a few ''K'', <math>M_J g_J \mu_\mathrm{B}H/k_\mathrm{B} T \ll 1</math>, and  we can apply the approximation <math>e^{M_J g_J \mu_\mathrm{B} H /k_\mathrm{B} T\;} \simeq 1 + M_J g_J \mu_\mathrm{B} H/k_\mathrm{B} T\;</math>:
<math display="block">\bar{m}=\frac{\sum\limits_{M_J=-J}^J {M_J g_J \mu_\mathrm{B} e^{M_J g_J \mu_\mathrm{B} H/k_\mathrm{B} T\;}}}{\sum\limits_{M_J=-J}^J e^{M_Jg_J\mu_\mathrm{B} H/k_\mathrm{B} T\;}}\simeq g_J\mu_\mathrm{B} \frac{\sum\limits_{M_J=-J}^J M_J \left( 1+M_J g_J\mu_\mathrm{B} H/k_\mathrm{B} T\; \right)}{\sum\limits_{M_J=-J}^J \left( 1+M_J g_J \mu_\mathrm{B} H/k_\mathrm{B} T \; \right)}=\frac{g_J^2 \mu_\mathrm{B}^2 H}{k_\mathrm{B} T} \frac{\sum\limits_{-J}^J M_J^2}{\sum\limits_{M_J=-J}^J{(1)}},</math>
which yields:
<math display="block">\bar{m}=\frac{g_J^2 \mu_\mathrm{B}^2 H}{3k_\mathrm{B} T} J(J+1).</math>
The bulk magnetization is then <math>M = n\bar{m} = \frac{n}{3k_\mathrm{B}T} \left[ g_J^2 J(J+1) \mu_\mathrm{B}^2 \right]H,</math> and the susceptibility is given by
<math display="block">\chi=\frac{\partial M_{\rm m}}{\partial H} = \frac{n}{3k_{\rm B} T} \mu_{\mathrm{eff}}^2 \text{  ;    and     } \mu_{\mathrm{eff}} = g_J \sqrt{J(J+1)} \mu_{\mathrm B}.</math>
}}

When orbital angular momentum contributions to the magnetic moment are small, as occurs for most [[Radical (chemistry)|organic radicals]] or for octahedral transition metal complexes with d<sup>3</sup> or high-spin d<sup>5</sup> configurations, the effective magnetic moment takes the form ( with [[G-factor (physics)|g-factor]] ''g''<sub>e</sub> = 2.0023... ≈ 2),
<math display="block">\mu_{\mathrm{eff}}\simeq 2\sqrt{S(S+1)} \mu_\mathrm{B} =\sqrt{N_{\rm u}(N_{\rm u}+2)} \mu_\mathrm{B},</math>
where ''N''<sub>u</sub> is the number of [[unpaired electron]]s.  In other transition metal complexes this yields a useful, if somewhat cruder, estimate.

When Curie constant is null, second order effects that couple the ground state with the excited states can also lead to a paramagnetic susceptibility independent of the temperature, known as [[Van Vleck paramagnetism|Van Vleck susceptibility]].

=== Pauli paramagnetism===
For some alkali metals and noble metals, conduction electrons are weakly interacting and delocalized in space forming a [[Fermi gas]]. For these materials one contribution to the magnetic response  comes from the interaction between the electron spins and the magnetic field known as Pauli paramagnetism. For a small magnetic field <math>\mathbf{H}</math>, the additional energy per electron from the interaction between an electron spin and the magnetic field is given by:

:<math>\Delta E= -\mu_0\mathbf{H}\cdot\boldsymbol{\mu}_e=- \mu_0\mathbf{H}\cdot\left(-g_e\frac{\mu_\mathrm{B}}{\hbar}\mathbf{S}\right)=\pm \mu_0 \mu_\mathrm{B} H,</math>

where <math>\mu_0</math> is the [[vacuum permeability]], <math>\boldsymbol{\mu}_e</math> is the [[electron magnetic moment]], <math>\mu_{\rm B}</math> is the [[Bohr magneton]], <math>\hbar</math> is the reduced Planck constant, and the [[g-factor (physics)|g-factor]] cancels with the spin <math>\mathbf{S}=\pm\hbar/2</math>. The <math>\pm</math> indicates that the sign is positive (negative) when the electron spin component in the direction of <math>\mathbf{H}</math> is parallel (antiparallel) to the magnetic field.
[[File:Pauli_2bis.jpg|thumb|right|In a metal, the application of an external magnetic field increases the density of electrons with spins antiparallel with the field and lowers the density of the electrons with opposite spin. Note: The arrows in this picture indicate spin direction, not magnetic moment.]]

For low temperatures with respect to the [[Fermi energy|Fermi temperature]] <math>T_{\rm F}</math> (around 10<sup>4</sup> [[kelvin]]s for metals), the [[number density]] of electrons <math>n_{\uparrow}</math> (<math>n_{\downarrow}</math>) pointing parallel (antiparallel) to the magnetic field can be written as:

:<math>n_{\uparrow}\approx\frac{n_e}{2}-\frac{\mu_0\mu_\mathrm{B}}{2}g(E_\mathrm{F})H\quad;\quad \left(n_{\downarrow}\approx\frac{n_e}{2}+\frac{\mu_0\mu_\mathrm{B}}{2}g(E_\mathrm{F})H\right),</math>

with <math>n_e</math> the total free-electrons density and <math>g(E_\mathrm{F})</math> the electronic density of states (number of states per energy per volume) at the [[Fermi energy]] <math>E_\mathrm{F}</math>.

In this approximation the magnetization is given as the magnetic moment of one electron times the difference in densities:

:<math>M=\mu_\mathrm{B}(n_{\downarrow}-n_{\uparrow})=\mu_0\mu_\mathrm{B}^2g(E_\mathrm{F})H,</math>

which yields a positive paramagnetic susceptibility independent of temperature:

:<math>\chi_\mathrm{P}=\mu_0\mu_\mathrm{B}^2g(E_\mathrm{F}).</math>

The Pauli paramagnetic susceptibility is a macroscopic effect and has to be contrasted with [[Landau diamagnetism|Landau diamagnetic susceptibility]] which is equal to minus one third of Pauli's and also comes from delocalized electrons. The Pauli susceptibility comes from the spin interaction with the magnetic field while the Landau susceptibility comes from the spatial motion of the electrons and it is independent of the spin. In doped semiconductors the ratio between Landau's and Pauli's susceptibilities changes as the [[effective mass (solid-state physics)|effective mass]] of the charge carriers <math>m^*</math> can differ from the electron mass <math>m_e</math>.

The magnetic response calculated for a gas of electrons is not the full picture as the magnetic susceptibility coming from the ions has to be included. Additionally, these formulas may break down for confined systems that differ from the bulk, like [[quantum dot]]s, or  for high fields, as demonstrated in the [[De Haas-Van Alphen effect]].

Pauli paramagnetism is named after the physicist [[Wolfgang Pauli]]. Before Pauli's theory, the lack of a strong Curie paramagnetism in metals was an open problem as the [[Drude model|leading Drude model]] could not account for this contribution without the use of [[Fermi–Dirac statistics|quantum statistics]].
Pauli paramagnetism and Landau diamagnetism are essentially applications of the spin and the [[free electron model]], the first is due to intrinsic spin of electrons; the second is due to their orbital motion.<ref>Pauli, Z.Phys. 41, 81, 1927</ref><ref>Landau, Z.Phys. 64, 629, 1930</ref>

==Examples of paramagnets==
Materials that are called "paramagnets" are most often those that exhibit, at least over an appreciable temperature range, magnetic susceptibilities that adhere to the Curie or Curie–Weiss laws. In principle any system that contains atoms, ions, or molecules with unpaired spins can be called a paramagnet, but the interactions between them need to be carefully considered.

===Systems with minimal interactions===
The narrowest definition would be: a system with unpaired spins that ''do not interact'' with each other. In this narrowest sense, the only pure paramagnet is a dilute gas of [[monatomic hydrogen]] atoms. Each atom has one non-interacting unpaired electron.

A gas of lithium atoms already possess two paired core electrons that produce a diamagnetic response of opposite sign. Strictly speaking Li is a mixed system therefore, although admittedly the diamagnetic component is weak and often neglected. In the case of heavier elements the diamagnetic contribution becomes more important and in the case of metallic gold it dominates the properties. The element hydrogen is virtually never called 'paramagnetic' because the monatomic gas is stable only at extremely high temperature; H atoms combine to form molecular H<sub>2</sub> and in so doing, the magnetic moments are lost (''quenched''), because of the spins pair. Hydrogen is therefore ''diamagnetic'' and the same holds true for many other elements. Although the electronic configuration of the individual atoms (and ions) of most elements contain unpaired spins, they are not necessarily paramagnetic, because at ambient temperature quenching is very much the rule rather than the exception. The quenching tendency is weakest for f-electrons because ''f'' (especially 4''f'') orbitals are radially contracted and they overlap only weakly with orbitals on adjacent atoms.  Consequently, the lanthanide elements with incompletely filled 4f-orbitals are paramagnetic or magnetically ordered.<ref>{{Cite book|url=http://www2.nbi.ku.dk/page40667.htm|title=Rare Earth Magnetism|author1=Jensen, J.|author2=MacKintosh, A. R.|name-list-style=amp|publisher=Clarendon Press|place=Oxford|year=1991|access-date=2009-07-12|archive-url=https://web.archive.org/web/20101212232011/http://www2.nbi.ku.dk/page40667.htm|archive-date=2010-12-12|url-status=dead}}</ref>

{|class="wikitable sortable" style="float:right; margin:20px" width="200px"
|+μ<sub>eff</sub> values for typical d<sup>3</sup> and d<sup>5</sup> transition metal complexes.<ref>Orchard, A. F. (2003) ''Magnetochemistry''. Oxford University Press.</ref>
!Material!!μ<sub>eff</sub>/μ<sub>B</sub>
|-
|[Cr(NH<sub>3</sub>)<sub>6</sub>]Br<sub>3</sub>||3.77
|-
|K<sub>3</sub>[Cr(CN)<sub>6</sub>]||3.87
|-
|K<sub>3</sub>[MoCl<sub>6</sub>]||3.79
|-
|K<sub>4</sub>[V(CN)<sub>6</sub>]||3.78
|-
|[Mn(NH<sub>3</sub>)<sub>6</sub>]Cl<sub>2</sub>||5.92
|-
|(NH<sub>4</sub>)<sub>2</sub>[Mn(SO<sub>4</sub>)<sub>2</sub>]·6H<sub>2</sub>O||5.92
|-
|NH<sub>4</sub>[Fe(SO<sub>4</sub>)<sub>2</sub>]·12H<sub>2</sub>O||5.89
|-
|}
Thus, condensed phase paramagnets are only possible if the interactions of the spins that lead either to quenching or to ordering are kept at bay by structural isolation of the magnetic centers. There are two classes of materials for which this holds:
*Molecular materials with a (isolated) paramagnetic center.
** Good examples are [[coordination complex]]es of d- or f-metals or proteins with such centers, e.g. [[myoglobin]]. In such materials the organic part of the molecule acts as an envelope shielding the spins from their neighbors.
** Small molecules can be stable in radical form, [[oxygen]] O<sub>2</sub> is a good example. Such systems are quite rare because they tend to be rather reactive.
* Dilute systems.
** Dissolving a  paramagnetic species in a diamagnetic lattice at small concentrations, e.g. Nd<sup>3+</sup> in CaCl<sub>2</sub> will separate the neodymium ions at large enough distances that they do not interact. Such systems are of prime importance for what can be considered the most sensitive method to study paramagnetic systems: [[Electron paramagnetic resonance|EPR]].

===Systems with interactions===
[[File:Para-ferro-anti.jpg|thumb|300px|Idealized Curie–Weiss behavior; N.B. T<sub>C</sub>=θ, but ''T''<sub>N</sub> is not θ. Paramagnetic regimes are denoted by solid lines. Close to ''T''<sub>N</sub> or ''T''<sub>C</sub> the behavior usually deviates from ideal.]]

As stated above, many materials that contain d- or f-elements do retain unquenched spins. Salts of such elements often show paramagnetic behavior but at low enough temperatures the magnetic moments may order. It is not uncommon to call such materials 'paramagnets', when referring to their paramagnetic behavior above their Curie or Néel-points, particularly if such temperatures are very low or have never been properly measured.  Even for iron it is not uncommon to say that ''iron becomes a paramagnet'' above its relatively high Curie-point. In that case the Curie-point is seen as a [[phase transition]] between a ferromagnet and a 'paramagnet'. The word paramagnet now merely refers to the linear response of the system to an applied field, the temperature dependence of which requires an amended version of Curie's law, known as the [[Curie–Weiss law]]:

:<math>\mathbf{M} = \frac{C}{T- \theta}\mathbf{H}</math>

This amended law includes a term θ that describes the exchange interaction that is present albeit overcome by thermal motion. The sign of θ depends on whether ferro- or antiferromagnetic interactions dominate and it is seldom exactly zero, except in the dilute, isolated cases mentioned above.

Obviously, the paramagnetic Curie–Weiss description above ''T''<sub>N</sub> or ''T''<sub>C</sub> is a rather different interpretation of the word "paramagnet" as it does ''not'' imply the ''absence'' of interactions, but rather that the [[magnetic structure]] is random in the absence of an external field at these sufficiently high temperatures. Even if ''θ'' is close to zero this does not mean that there are no interactions, just that the aligning ferro- and the anti-aligning antiferromagnetic ones cancel. An additional complication is that the interactions are often different in different directions of the crystalline lattice ([[anisotropy]]), leading to complicated [[magnetic structure]]s once ordered.

Randomness of the structure also applies to the many metals that show a net paramagnetic response over a broad temperature range. They do not follow a Curie type law as function of temperature however; often they are more or less temperature independent. This type of behavior is of an itinerant nature and better called Pauli-paramagnetism, but it is not unusual to see, for example, the metal [[aluminium]] called a "paramagnet", even though interactions are strong enough to give this element very good electrical conductivity.

===Superparamagnets===
Some materials show induced magnetic behavior that follows a Curie type law but with exceptionally large values for the Curie constants. These materials are known as [[superparamagnetism|superparamagnets]]. They are characterized by a strong ferromagnetic or ferrimagnetic type of coupling into domains of a limited size that behave independently from one another. The bulk properties of such a system resembles that of a paramagnet, but on a microscopic level they are ordered. The materials do show an ordering temperature above which the behavior reverts to ordinary paramagnetism (with interaction). [[Ferrofluid]]s are a good example, but the phenomenon can also occur inside solids, e.g., when dilute paramagnetic centers are introduced in a strong itinerant medium of ferromagnetic coupling such as when Fe is substituted in TlCu<sub>2</sub>Se<sub>2</sub> or the alloy AuFe. Such systems contain ferromagnetically coupled clusters that freeze out at lower temperatures. They are also called [[mictomagnetism|mictomagnets]].

==See also==
*[[Magnetochemistry]]

==References==
{{reflist|refs=
<ref name=brit>[http://global.britannica.com/EBchecked/topic/442927/paramagnetism paramagnetism].  Encyclopædia Britannica</ref>
}}

==Further reading==
* [https://feynmanlectures.caltech.edu/II_35.html The Feynman Lectures on Physics Vol. II Ch. 35: Paramagnetism and Magnetic Resonance]
* Charles Kittel, ''[[Introduction to Solid State Physics]]'' (Wiley: New York, 1996).
* John David Jackson, ''Classical Electrodynamics'' (Wiley: New York, 1999).

==External links==
*{{Commons category-inline}}
* [https://web.archive.org/web/20150923210131/http://www.cond-mat.de/events/correl13/manuscripts/pavarini.pdf Magnetism: Models and Mechanisms] in E.  Pavarini, E. Koch, and U. Schollwöck: Emergent Phenomena in Correlated Matter, Jülich 2013, {{ISBN|978-3-89336-884-6}}

{{magnetic states}}

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