Technomimetics
Technomimetics are molecular systems that can mimic man-made devices. The term was first introduced in 1997.<ref name=Gakh>Gakh, A.A.; Sachleben, R.A.; and Bryan, J.C. Molecular gearing systems. ChemTech, 1997, 27(11), 26-33.</ref> The current set of technomimetic molecules<ref name=Rapenne>Rapenne, G. Synthesis of technomimetic molecules: Towards rotation control in single molecular machines and motors. Org. Biomol. Chem. 2005, 3, 1165-1169. doi:10.1039/b419282f</ref> includes motors,<ref name= Fletcher>Fletcher, S. P.; Dumur, F.; Pollard, M. M.; Feringa, B. L. A Reversible, Unidirectional Molecular Rotary Motor Driven by Chemical Energy. Science, 2005, 310(5745), 80-82. doi:10.1126/science.1117090</ref> rotors,<ref name=Kottas>Kottas, G.S.; Clarke, L. I.; Horinek, D.; Michl, J. Artificial molecular rotors. Chem. Rev. 2005, 105, 1281-1376. doi:10.1021/cr0300993</ref> gears,<ref name= Manzano>Manzano, C.; Soe, W.-H.; Wong, H. S.; Ample, F.; Gourdon, A.; Chandrasekhar, N.; Joachim, C. Step-by-step rotation of a molecule-gear mounted on an atomic-scale axis. Nature Materials, 2009, 8, 576-579. doi:10.1038/NMAT2467</ref> gyroscopes,<ref name=Shima>Shima, T.; Hampel, F.; Gladysz, J.A. Molecular Gyroscopes: Fe(CO)3 and Fe(CO)2-(NO)+ Rotators Encased in Three-Spoke Stators; Facile Assembly via Alkene Metatheses. Angew. Chem. Int. Ed. 2004, 43, 5537-5540. doi:10.1002/anie.200460534</ref> tweezers,<ref name= Chen>Chen C.-W.; Whitlock H. W. Molecular Tweezers - A Simple-Model of Bifunctional Intercalation. J. Am. Chem. Soc. 1978, 100, 4921–4922. doi:10.1021/ja00483a063</ref> and other molecular devices. Technomimetics can be considered as the essential components of molecular machines and have the primary use in molecular nanotechnology.
