Radionuclide

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Not to be confused with radionucleotide.

A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess numbers of either neutrons or protons, giving it excess nuclear energy, and making it unstable. This excess energy can be used in one of three ways: emitted from the nucleus as gamma radiation; transferred to one of its electrons to release it as a conversion electron; or used to create and emit a new particle (alpha particle or beta particle) from the nucleus. During those processes, the radionuclide is said to undergo radioactive decay.<ref>Petrucci, R. H.; Harwood, W. S.; Herring, F. G. (2002). General Chemistry (8th ed.). Prentice-Hall. pp. 1025–26. ISBN 0-13-014329-4.</ref> These emissions are considered ionizing radiation because they are energetic enough to liberate an electron from another atom. The radioactive decay can produce a stable nuclide or will sometimes produce a new unstable radionuclide which may undergo further decay. Radioactive decay is a random process at the level of single atoms: it is impossible to predict when one particular atom will decay.<ref name="not-predict">"Decay and Half Life". Retrieved 2009-12-14.</ref><ref name="IntroductionToHealthPhysics">Stabin, Michael G. (2007). "3". In Stabin, Michael G (ed.). Radiation Protection and Dosimetry: An Introduction to Health Physics (Submitted manuscript). Springer. doi:10.1007/978-0-387-49983-3. ISBN 978-0387499826.</ref><ref name="RadiationOncologyPrimer">Best, Lara; Rodrigues, George; Velker, Vikram (2013). "1.3". Radiation Oncology Primer and Review. Demos Medical Publishing. ISBN 978-1620700044.</ref><ref>Loveland, W.; Morrissey, D.; Seaborg, G.T. (2006). Modern Nuclear Chemistry. Wiley-Interscience. p. 57. Bibcode:2005mnc..book.....L. ISBN 978-0-471-11532-8.</ref> However, for a collection of atoms of a single nuclide the decay rate, and thus the half-life (t1/2) for that collection, can be calculated from their measured decay constants. The range of the half-lives of radioactive atoms has no known limits and spans a time range of over 55 orders of magnitude.

Radionuclides occur naturally or are artificially produced in nuclear reactors, cyclotrons, particle accelerators or radionuclide generators. There are about 730 radionuclides with half-lives longer than 60 minutes (see list of nuclides). Thirty-two of those are primordial radionuclides that were created before the Earth was formed. At least another 60 radionuclides are detectable in nature, either as daughters of primordial radionuclides or as radionuclides produced through natural production on Earth by cosmic radiation. More than 2400 radionuclides have half-lives less than 60 minutes. Most of those are only produced artificially, and have very short half-lives. For comparison, there are about 251 stable nuclides. (In theory, only 146 of them are stable, and the other 105 are believed to decay via alpha decay, beta decay, double beta decay, electron capture, or double electron capture.)

All chemical elements can exist as radionuclides. Even the lightest element, hydrogen, has a well-known radionuclide, tritium. Elements heavier than lead, and the elements technetium and promethium, exist only as radionuclides. (In theory, elements heavier than dysprosium exist only as radionuclides, but some such elements, like gold and platinum, are observationally stable and their half-lives have not been determined).

Unplanned exposure to radionuclides generally has a harmful effect on living organisms including humans, although low levels of exposure occur naturally without harm. The degree of harm will depend on the nature and extent of the radiation produced, the amount and nature of exposure (close contact, inhalation or ingestion), and the biochemical properties of the element; with increased risk of cancer the most usual consequence. However, radionuclides with suitable properties are used in nuclear medicine for both diagnosis and treatment. An imaging tracer made with radionuclides is called a radioactive tracer. A pharmaceutical drug made with radionuclides is called a radiopharmaceutical.

Origin

Natural

On Earth, naturally occurring radionuclides fall into three categories: primordial radionuclides, secondary radionuclides, and cosmogenic radionuclides.

  • Radionuclides are produced in stellar nucleosynthesis and supernova explosions along with stable nuclides. Most decay quickly but can still be observed astronomically and can play a part in understanding astronomic processes. Primordial radionuclides, such as uranium and thorium, exist in the present time because their half-lives are so long (>100 million years) that they have not yet completely decayed. Some radionuclides have half-lives so long (many times the age of the universe) that decay has only recently been detected, and for most practical purposes they can be considered stable, most notably bismuth-209: detection of this decay meant that bismuth was no longer considered stable. It is possible decay may be observed in other nuclides, adding to this list of primordial radionuclides.
  • Secondary radionuclides are radiogenic isotopes derived from the decay of primordial radionuclides. They have shorter half-lives than primordial radionuclides. They arise in the decay chain of the primordial isotopes thorium-232, uranium-238, and uranium-235. Examples include the natural isotopes of polonium and radium.
  • Cosmogenic isotopes, such as carbon-14, are present because they are continually being formed in the atmosphere due to cosmic rays.<ref>Eisenbud, Merril; Gesell, Thomas F (1997-02-25). Environmental Radioactivity: From Natural, Industrial, and Military Sources. Elsevier. p. 134. ISBN 9780122351549.</ref>

Many of these radionuclides exist only in trace amounts in nature, including all cosmogenic nuclides. Secondary radionuclides will occur in proportion to their half-lives, so short-lived ones will be very rare. For example, polonium can be found in uranium ores at about 0.1 mg per metric ton (1 part in 1010).<ref>Bagnall, K. W. (1962). "The Chemistry of Polonium". Advances in Inorganic Chemistry and Radiochemistry 4. New York: Academic Press. pp. 197–226. doi:10.1016/S0065-2792(08)60268-X. ISBN 0-12-023604-4. Retrieved June 14, 2012., p. 746</ref><ref>Bagnall, K. W. (1962). "The Chemistry of Polonium". Advances in Inorganic Chemistry and Radiochemistry 4. New York: Academic Press., p. 198</ref> Further radionuclides may occur in nature in virtually undetectable amounts as a result of rare events such as spontaneous fission or uncommon cosmic ray interactions.

Nuclear fission

Radionuclides are produced as an unavoidable result of nuclear fission and thermonuclear explosions. The process of nuclear fission creates a wide range of fission products, most of which are radionuclides. Further radionuclides can be created from irradiation of the nuclear fuel (creating a range of actinides) and of the surrounding structures, yielding activation products. This complex mixture of radionuclides with different chemistries and radioactivity makes handling nuclear waste and dealing with nuclear fallout particularly problematic.[citation needed]

Synthetic

Artificial nuclide americium-241 emitting alpha particles inserted into a cloud chamber for visualisation

Synthetic radionuclides are deliberately synthesised using nuclear reactors, particle accelerators or radionuclide generators:[citation needed]

  • As well as being extracted from nuclear waste, radioisotopes can be produced deliberately with nuclear reactors, exploiting the high flux of neutrons present. These neutrons activate elements placed within the reactor. A typical product from a nuclear reactor is iridium-192. The elements that have a large propensity to take up the neutrons in the reactor are said to have a high neutron cross-section.
  • Particle accelerators such as cyclotrons accelerate particles to bombard a target to produce radionuclides. Cyclotrons accelerate protons at a target to produce positron-emitting radionuclides, e.g. fluorine-18.
  • Radionuclide generators contain a parent radionuclide that decays to produce a radioactive daughter. The parent is usually produced in a nuclear reactor. A typical example is the technetium-99m generator used in nuclear medicine. The parent produced in the reactor is molybdenum-99.

Uses

Radionuclides are used in two major ways: either for their radiation alone (irradiation, nuclear batteries) or for the combination of chemical properties and their radiation (tracers, biopharmaceuticals).

Examples

The following table lists properties of selected radionuclides illustrating the range of properties and uses.

Isotope Z N half-life DM DE
keV		 Mode of formation Comments
Tritium (3H) 1 2 12.3 y β− 19 Cosmogenic lightest radionuclide, used in artificial nuclear fusion, also used for radioluminescence and as oceanic transient tracer. Synthesized from neutron bombardment of lithium-6 or deuterium
Beryllium-10 4 6 1,387,000 y β− 556 Cosmogenic used to examine soil erosion, soil formation from regolith, and the age of ice cores
Carbon-14 6 8 5,700 y β− 156 Cosmogenic used for radiocarbon dating
Fluorine-18 9 9 110 min β+, EC 633/1655 Cosmogenic positron source, synthesised for use as a medical radiotracer in PET scans.
Aluminium-26 13 13 717,000 y β+, EC 4004 Cosmogenic exposure dating of rocks, sediment
Chlorine-36 17 19 301,000 y β−, EC 709 Cosmogenic exposure dating of rocks, groundwater tracer
Potassium-40 19 21 1.24×109 y β−, EC 1330 /1505 Primordial used for potassium-argon dating, source of atmospheric argon, source of radiogenic heat, largest source of natural radioactivity
Calcium-41 20 21 99,400 y EC Cosmogenic exposure dating of carbonate rocks
Cobalt-60 27 33 5.3 y β− 2824 Synthetic produces high energy gamma rays, used for radiotherapy, equipment sterilisation, food irradiation
Krypton-81 36 45 229,000 y β+ Cosmogenic groundwater dating
Strontium-90 38 52 28.8 y β− 546 Fission product medium-lived fission product; probably most dangerous component of nuclear fallout
Technetium-99 43 56 210,000 y β− 294 Fission product most common isotope of the lightest unstable element, most significant of long-lived fission products
Technetium-99m 43 56 6 hr γ,IC 141 Synthetic most commonly used medical radioisotope, used as a radioactive tracer
Iodine-129 53 76 15,700,000 y β− 194 Cosmogenic longest lived fission product; groundwater tracer
Iodine-131 53 78 8 d β− 971 Fission product most significant short-term health hazard from nuclear fission, used in nuclear medicine, industrial tracer
Xenon-135 54 81 9.1 h β− 1160 Fission product strongest known "nuclear poison" (neutron-absorber), with a major effect on nuclear reactor operation.
Caesium-137 55 82 30.2 y β− 1176 Fission product other major medium-lived fission product of concern
Gadolinium-153 64 89 240 d EC Synthetic Calibrating nuclear equipment, bone density screening
Bismuth-209 83 126 2.01×1019y α 3137 Primordial long considered stable, decay only detected in 2003
Polonium-210 84 126 138 d α 5307 Decay product Highly toxic, used in poisoning of Alexander Litvinenko
Radon-222 86 136 3.8 d α 5590 Decay product gas, responsible for the majority of public exposure to ionizing radiation, second most frequent cause of lung cancer
Thorium-232 90 142 1.4×1010 y α 4083 Primordial basis of thorium fuel cycle
Uranium-235 92 143 7×108y α 4679 Primordial fissile, main nuclear fuel
Uranium-238 92 146 4.5×109 y α 4267 Primordial Main Uranium isotope
Plutonium-238 94 144 87.7 y α 5593 Synthetic used in radioisotope thermoelectric generators (RTGs) and radioisotope heater units as an energy source for spacecraft
Plutonium-239 94 145 24,110 y α 5245 Synthetic used for most modern nuclear weapons
Americium-241 95 146 432 y α 5486 Synthetic used in household smoke detectors as an ionising agent
Californium-252 98 154 2.64 y α/SF 6217 Synthetic undergoes spontaneous fission (3% of decays), making it a powerful neutron source, used as a reactor initiator and for detection devices

Key: Z = atomic number; N = neutron number; DM = decay mode; DE = decay energy; EC = electron capture

Household smoke detectors

Americium-241 container in a smoke detector.
Americium-241 capsule as found in smoke detector. The circle of darker metal in the center is americium-241; the surrounding casing is aluminium.

Radionuclides are present in many homes as they are used inside the most common household smoke detectors. The radionuclide used is americium-241, which is created by bombarding plutonium with neutrons in a nuclear reactor. It decays by emitting alpha particles and gamma radiation to become neptunium-237. Smoke detectors use a very small quantity of 241Am (about 0.29 micrograms per smoke detector) in the form of americium dioxide. 241Am is used as it emits alpha particles which ionize the air in the detector's ionization chamber. A small electric voltage is applied to the ionized air which gives rise to a small electric current. In the presence of smoke, some of the ions are neutralized, thereby decreasing the current, which activates the detector's alarm.<ref>"Smoke Detectors and Americium". world-nuclear.org. Archived from the original on 2010-11-12.</ref><ref>Office of Radiation Protection – Am 241 Fact Sheet – Washington State Department of Health Archived 2011-03-18 at the Wayback Machine</ref>

Impacts on organisms

Radionuclides that find their way into the environment may cause harmful effects as radioactive contamination. They can also cause damage if they are excessively used during treatment or in other ways exposed to living beings, by radiation poisoning. Potential health damage from exposure to radionuclides depends on a number of factors, and "can damage the functions of healthy tissue/organs. Radiation exposure can produce effects ranging from skin redness and hair loss, to radiation burns and acute radiation syndrome. Prolonged exposure can lead to cells being damaged and in turn lead to cancer. Signs of cancerous cells might not show up until years, or even decades, after exposure."<ref name="Fact sheet N°371">"Ionizing radiation, health effects and protective measures". World Health Organization. November 2012. Retrieved January 27, 2014.</ref>

Summary table for classes of nuclides, stable and radioactive

Following is a summary table for the list of 989 nuclides with half-lives greater than one hour. A total of 251 nuclides have never been observed to decay, and are classically considered stable. Of these, 90 are believed to be absolutely stable except to proton decay (which has never been observed), while the rest are "observationally stable" and theoretically can undergo radioactive decay with extremely long half-lives.

The remaining tabulated radionuclides have half-lives longer than 1 hour, and are well-characterized (see list of nuclides for a complete tabulation). They include 30 nuclides with measured half-lives longer than the estimated age of the universe (13.8 billion years<ref>"Cosmic Detectives". The European Space Agency (ESA). 2013-04-02. Retrieved 2013-04-15.</ref>), and another four nuclides with half-lives long enough (> 100 million years) that they are radioactive primordial nuclides, and may be detected on Earth, having survived from their presence in interstellar dust since before the formation of the Solar System, about 4.6 billion years ago. Another 60+ short-lived nuclides can be detected naturally as daughters of longer-lived nuclides or cosmic-ray products. The remaining known nuclides are known solely from artificial nuclear transmutation.

Numbers are not exact, and may change slightly in the future, as "stable nuclides" are observed to be radioactive with very long half-lives.

This is a summary table<ref>Table data is derived by counting members of the list; see WP:CALC. References for the list data itself are given below in the reference section in list of nuclides</ref> for the 989 nuclides with half-lives longer than one hour (including those that are stable), given in list of nuclides.

Stability class Number of nuclides Running total Notes on running total
Theoretically stable to all but proton decay 90 90 Includes first 40 elements. Proton decay yet to be observed.
Theoretically stable to alpha decay, beta decay, isomeric transition, and double beta decay but not spontaneous fission, which is possible for "stable" nuclides ≥ niobium-93 56 146 All nuclides that are possibly completely stable (spontaneous fission has never been observed for nuclides with mass number < 232).
Energetically unstable to one or more known decay modes, but no decay yet seen. All considered "stable" until decay detected. 105 251 Total of classically stable nuclides.
Radioactive primordial nuclides. 35 286 Total primordial elements include uranium, thorium, bismuth, rubidium-87, potassium-40, tellurium-128 plus all stable nuclides.
Radioactive nonprimordial, but naturally occurring on Earth. 61 347 Carbon-14 (and other isotopes generated by cosmic rays) and daughters of radioactive primordial elements, such as radium, polonium, etc. 41 of these have a half life of greater than one hour.
Radioactive synthetic half-life ≥ 1.0 hour). Includes most useful radiotracers. 662 989 These 989 nuclides are listed in the article List of nuclides.
Radioactive synthetic (half-life < 1.0 hour). >2400 >3300 Includes all well-characterized synthetic nuclides.

List of commercially available radionuclides

See also: List of nuclides and Table of nuclides

This list covers common isotopes, most of which are available in very small quantities to the general public in most countries. Others that are not publicly accessible are traded commercially in industrial, medical, and scientific fields and are subject to government regulation.

Gamma emission only

Isotope Activity Half-life Energies (keV)
Barium-133 9694 TBq/kg (262 Ci/g) 10.7 years 81.0, 356.0
Cadmium-109 96200 TBq/kg (2600 Ci/g) 453 days 88.0
Cobalt-57 312280 TBq/kg (8440 Ci/g) 270 days 122.1
Cobalt-60 40700 TBq/kg (1100 Ci/g) 5.27 years 1173.2, 1332.5
Europium-152 6660 TBq/kg (180 Ci/g) 13.5 years 121.8, 344.3, 1408.0
Manganese-54 287120 TBq/kg (7760 Ci/g) 312 days 834.8
Sodium-22 237540 Tbq/kg (6240 Ci/g) 2.6 years 511.0, 1274.5
Zinc-65 304510 TBq/kg (8230 Ci/g) 244 days 511.0, 1115.5
Technetium-99m 1.95×107 TBq/kg (5.27 × 105 Ci/g) 6 hours 140

Beta emission only

Isotope Activity Half-life Energies (keV)
Strontium-90 5180 TBq/kg (140 Ci/g) 28.5 years 546.0
Thallium-204 17057 TBq/kg (461 Ci/g) 3.78 years 763.4
Carbon-14 166.5 TBq/kg (4.5 Ci/g) 5730 years 49.5 (average)
Tritium (Hydrogen-3) 357050 TBq/kg (9650 Ci/g) 12.32 years 5.7 (average)

Alpha emission only

Isotope Activity Half-life Energies (keV)
Polonium-210 166500 TBq/kg (4500 Ci/g) 138.376 days 5304.5
Uranium-238 12580 kBq/kg (0.00000034 Ci/g) 4.468 billion years 4267

Multiple radiation emitters

Isotope Activity Half-life Radiation types Energies (keV)
Caesium-137 3256 TBq/kg (88 Ci/g) 30.1 years Gamma & beta G: 32, 661.6 B: 511.6, 1173.2
Americium-241 129.5 TBq/kg (3.5 Ci/g) 432.2 years Gamma & alpha G: 59.5, 26.3, 13.9 A: 5485, 5443

See also

Notes

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References

Further reading

External links

Wikimedia Commons has media related to Radionuclides.

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